My specific knowledge of Ford stuff ended at that truck, just restarted with a 2017 6.7, but totally different stuff.
What I am suggesting is that you jump into the way back machine and find some late 60's parts, or modern copies. The original versions of that motor were designed for load hauling, low torque applications. They changed the heads and tune around 1970 for higher RPM performance and then the mid 70's oil embargo and emissions issues gave us nothing but crap. If you read the hot rod mags you will find that everyone throws the late 60's stuff away to "Hot Rod" the motor. For a direct drive application, knowing nothing else, you should read the Hot Rod advice on opposite day, do the exact opposite.
Without going the custom grind route, I am guessing (seriously guessing) you will not find the cam you really want new. Ebay is where I would go, there has to be someone trying to unload that 69 old school cam so they can put in the Extreme Energy stuff. I mean who wants a cam that runs out of wind at 3,500 :!:
On the subject of heads, note the comment about higher compression. Generally the easiest way to do this is by using heads from the same block, but smaller bore. There are plenty of high compression 302 heads out there. With 0 research on the subject, the 302 is where I would start. Again, I would check ebay for someone upgrading for higher rpm/flow. Port match them and run a burr grinder around the runners to rough them up as best you can. If you are ready to spend aluminum head money that is ok, but assume it is all for weight savings other than larger valves and make sure the volume is correct for good compression (10+-1). For a direct drive, compression vs. valve size, compression give the most bang for buck. You can get small chamber volume in cast iron off ebay etc.
Add in a 69' stock low lift cam, a 500 cfm max carb and mechanical advance all in way early and you are there. Build it for premium and tune accordingly.
That's the best advice I can give without research, use with grains of salt.